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Question: Answered & Verified by Expert
The rate constant of a first order reaction at $27^{\circ} \mathrm{C}$ is $10^{-3} \mathrm{~min}^{-1}$. The temperature coefficient of this reaction is 2 . What is the rate constant (in $\mathrm{min}^{-1}$ ) at $17^{\circ} \mathrm{C}$ for this reaction?
ChemistryChemical KineticsTS EAMCETTS EAMCET 2006
Options:
  • A $10^{-3}$
  • B $5 \times 10^{-4}$
  • C $2 \times 10^{-3}$
  • D $10^{-2}$
Solution:
1509 Upvotes Verified Answer
The correct answer is: $5 \times 10^{-4}$
Temperature coefficient, $=\frac{k_t+10}{k_t}$
$2=\frac{10^{-3}}{k_t}$
$k_t=\frac{10^{-3}}{2}=\frac{10 \times 10^{-4}}{2}=5 \times 10^{-4}$

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