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Question: Answered & Verified by Expert
The ratio a/b (the terms used in van der Waal's equation) has the unit
ChemistryStates of MatterNEET
Options:
  • A atm litre mol-1
  • B atm dm3mol-1
  • C dyne cm mol-1
  • D All of these
Solution:
2242 Upvotes Verified Answer
The correct answer is: All of these
P+ a n 2 v 2 vnb =nRT
The units of 'a' = atm litre2mol-2
=atdmmol-2=dyncm2mol-2
And the untis of 'b' = litre mol-1 = m3mol-1 =cm3mol-1
Hence, unit of a/b = atm litre2mol-1 / litre mol-1=atlitrmol-1
Similarly all other units are possible.

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