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Question: Answered & Verified by Expert
The reaction is:
ChemistryAlcohols Phenols and EthersJEE Main
Options:
  • A $\mathrm{CH}_3 \mathrm{CHOHCH}_3$
  • B $\mathrm{CH}_3 \mathrm{COCH}_3$
  • C $\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}$
  • D $\mathrm{CH}_3 \mathrm{COOH}$
Solution:
1914 Upvotes Verified Answer
The correct answer is: $\mathrm{CH}_3 \mathrm{COCH}_3$
The reaction shows a two-step process:
- In the first step, potassium dichromate ($\mathrm{K} 2 \mathrm{Cr} 2 \mathrm{O}_7)$) oxidizes the alcohol (reactant A) to a ketone or aldehyde in the presence of dilute sulfuric acid (H2SO4).
- In the second step, the ketone or aldehyde is reduced to a primary alcohol by methylmagnesium iodide (CH3Mgl) in water ($\mathrm{H} 2 \mathrm{O})$.

The reactant $\mathrm{A}, \mathrm{C} 2 \mathrm{H} 5 \mathrm{OH}$, is ethanol, a primary alcohol. The product of the first step is acetaldehyde, a ketone. The second step reduces the ketone to propanol, another primary alcohol.

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