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Question: Answered & Verified by Expert
The reaction of white phosphorus with aqueous NaOH gives phosphine along with another phosphorus containing compound. The reaction type; the oxidation state of phosphorus in phosphine and the other product are respectively
Chemistryp Block Elements (Group 15, 16, 17 & 18)NEET
Options:
  • A Redox reaction; +3 and +5
  • B Redox reaction; -3 and – 5
  • C Disproportionation reaction; - 3 and +3
  • D Disproportionation reaction; - 3 and +1
Solution:
1017 Upvotes Verified Answer
The correct answer is: Disproportionation reaction; - 3 and +3
The reaction of white phosphorus with aqueous NaOH gives phosphine along with sodium hydrogen phosphite. It is Disproportionation reaction in which oxidation number of phosphorus is changing from 0 to -3 and +3 as follows
P 4 0 +NaOH aq PH 3 3 + Na 2 HPO 3 +3

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