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Question: Answered & Verified by Expert
The reaction, RNH2+CHCl3+3KOHEthanolicR-N+C- +3KCl+3H2O is called
ChemistryAminesNEET
Options:
  • A Cope reaction
  • B Curtius reaction
  • C Hoffmann-bromamide reaction
  • D Carbylamine reaction
Solution:
2660 Upvotes Verified Answer
The correct answer is: Carbylamine reaction
The reaction, RNH2+CHCl3+3KOHEthanolicR-N+C- +3KCl+3H2O is called Carbylamine reaction

Mechanism CHCl 3 +KOH CCl 2 (Electrophilic carbene) + H 2 O+KCl

R-N. .H2+:CCl2R-+N | |  H  H-C||:-Cl  Cl  2KOH-2HClR-N+C-

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