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Question: Answered & Verified by Expert
The "spin only" magnetic moment of $\mathrm{Ni}^{2+}$ in aqueous solution would be [At. no. of $\mathrm{Ni}=28$ ]
ChemistryCoordination CompoundsKCETKCET 2012
Options:
  • A $\sqrt{15} \mathrm{BM}$
  • B $\sqrt{2} \mathrm{BM}$
  • C $\sqrt{8} \mathrm{BM}$
  • D $\sqrt{6} \mathrm{BM}$
Solution:
2379 Upvotes Verified Answer
The correct answer is: $\sqrt{8} \mathrm{BM}$
$\mathrm{Ni}^{2+}$ in aqueous solution refers to
${\left.\left[\mathrm{Ni}_{2} \mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+} \cdot \mathrm{Ni}^{2+}$ has following electronic $}
$ orientation.



$\therefore$ Number of unpaired electrons $=2$
Spin only magnetic moment $=\sqrt{n(n+2)}$
$$
=\sqrt{2(2+2)}=\sqrt{8} \mathrm{BM}
$$

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