Join the Most Relevant JEE Main 2025 Test Series & get 99+ percentile! Join Now
Search any question & find its solution
Question: Answered & Verified by Expert
The structure of PCC is
ChemistryGeneral Organic ChemistryTS EAMCETTS EAMCET 2013
Options:
  • A $\mathrm{C}_6 \mathrm{H}_5 \stackrel{\oplus}{\mathrm{N}} \mathrm{HCrO}_2 \mathrm{Cl}^{\ominus}$
  • B $\mathrm{C}_6 \mathrm{H}_5 \stackrel{\oplus}{\mathrm{N}} \mathrm{HCrO}_3 \mathrm{Cl}^{\ominus}$
  • C $\mathrm{C}_5 \mathrm{H}_5 \stackrel{\oplus}{\mathrm{N}} \mathrm{HCrO}_2 \mathrm{Cl}^{\ominus}$
  • D $\mathrm{C}_5 \mathrm{H}_5 \stackrel{\oplus}{\mathrm{N}} \mathrm{HCrO}_3 \mathrm{Cl}^{\ominus}$
Solution:
2506 Upvotes Verified Answer
The correct answer is: $\mathrm{C}_5 \mathrm{H}_5 \stackrel{\oplus}{\mathrm{N}} \mathrm{HCrO}_3 \mathrm{Cl}^{\ominus}$
Pyridinium chlorochromate (PCC) can be prepared by the dissolution of chromium trioxide in aqueous $\mathrm{HCl}$. Addition of pyridine gives pridinium chlorochromate as orange cryotol.


PCC offers the advantage of the selective oxidation of alcohols to aldehydes, whereas many other reagents are less selective.

Looking for more such questions to practice?

Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.