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Question: Answered & Verified by Expert
The suitable reagents for the conversion of methane into methyl iodide are
ChemistryHydrocarbonsAP EAMCETAP EAMCET 2021 (23 Aug Shift 1)
Options:
  • A $\mathrm{I}_2, \mathrm{HNO}_2$
  • B $\mathrm{I}_2, \mathrm{H}_2 \mathrm{O}_2$
  • C $\mathrm{I}_2, \mathrm{H}_2 \mathrm{O}$
  • D $\mathrm{I}_2, \mathrm{HNO}_3$
Solution:
1649 Upvotes Verified Answer
The correct answer is: $\mathrm{I}_2, \mathrm{HNO}_3$
$\mathrm{CH}_4+\mathrm{I}_2 \rightleftharpoons \mathrm{CH}_3 \mathrm{I}+\mathrm{HI}$
Since, it is reversible process.
Therefore, $\mathrm{HNO}_3$ is used to convert $\mathrm{HI}$ into $\mathrm{I}_2$.
$$
2 \mathrm{HNO}_3+2 \mathrm{HI} \longrightarrow 2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O}+\mathrm{I}_2
$$

So, $\mathrm{I}_2$ and $\mathrm{HNO}_3$ are suitable reagents.

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