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Question: Answered & Verified by Expert
The temperature coefficient of e.m.f of a cell can be given by:
ChemistryThermodynamics (C)JEE Main
Options:
  • A ETP=ΔSnF
  • B ETP=E2-E1T2-T1
  • C ETP=ΔΗnF+E·1T
  • D All of these
Solution:
1847 Upvotes Verified Answer
The correct answer is: All of these
ΔG=ΔH+TΔGTP (Gibbs-Helmholz equation)
Also, ΔG=ΔH-TΔS; and -ΔG=nF·E
or -TΔS=TΔGTP=T-nFETP
or ETP=ΔSnF, similarly derive for other values.

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