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The total number of $\sigma$ and $\pi$-bonds in pyrophosphoric acid are respectively
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12, 2
The structure of pyrophosphoric acid $\left(\mathrm{H}_4 \mathrm{P}_2 \mathrm{O}_7\right)$ is as

Hence, it contains $12 \sigma$ and $2 \pi$-bonds.

Hence, it contains $12 \sigma$ and $2 \pi$-bonds.
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