The treatment of acylazide (RCON 3 ) with acidic or alkaline medium gives

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The treatment of acylazide (RCON $_{3}$ ) with acidic or alkaline medium gives

ChemistryAminesVITEEEVITEEE 2006

Options:

A $\mathrm{RCONH}_{2}$
B $\mathrm{R}-\mathrm{NH}_{2}$
C $\mathrm{RCH}_{2} \mathrm{NH}_{2}$.
D $\mathrm{RCOCHNH}$

Solution:

1936 Upvotes Verified Answer

The correct answer is: $\mathrm{R}-\mathrm{NH}_{2}$

This reaction is known as curtius rearrangement.

$1^{\circ}$ amine is formed.

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