Join the Most Relevant JEE Main 2025 Test Series & get 99+ percentile! Join Now
Search any question & find its solution
Question: Answered & Verified by Expert
The two electrons have the following set of quantum numbers :
\[
\begin{array}{l}
P=3,2,-2,+\frac{1}{2} \\
Q=3,0,0,+\frac{1}{2}
\end{array}
\]
Which of the following statement is true?
ChemistryStructure of AtomKCETKCET 2015
Options:
  • A \( P \) and \( Q \) have same energy
  • B \( P \) has greater energy than \( Q \)
  • C \( P \) has lesser energy than \( Q \)
  • D \( \mathrm{P} \) and \( \mathrm{Q} \) represent same electron
Solution:
1074 Upvotes Verified Answer
The correct answer is: \( P \) has greater energy than \( Q \)
For electron $P$, the values of quantum numbers are $n=3, I=2, m l=-2$ and $s=+1 / 2$. For electron $Q$ quantum numbers are $n=3, I=0, m l=0$ and $s=+1 / 2$. Therefore, from the quantum number values, electron $P$ belongs to $3 d-$ orbital and electron $Q$ to $3 s$ - orbital. Energy of the orbital is $s < p < d < f$.
Hence, energy of electron $P$ is higher than electron $Q$.

Looking for more such questions to practice?

Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.