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Question: Answered & Verified by Expert
The work done in an open vessel at 300 K, when 112 g iron reacts with dil. HCl is ( R = 2 cal mol-1 K-1 )
ChemistryThermodynamics (C)JEE Main
Options:
  • A 1200 cal
  • B 600 cal
  • C 300 cal
  • D 200 cal
Solution:
2204 Upvotes Verified Answer
The correct answer is: 1200 cal
Fe + 2 HCl FeCl 2 + H 2 1 mol 1 mol 1 1 2 5 6 = 2 mol 2 mol

Now, V 2 = V H 2   and  V 1 = 0      (For solid + aqueous state)

Work done = - p ext Δ V

                  =Δ(PV)= n H 2 RT

                  = - 2 × 2 × 3 0 0

                  = - 1200 cals (Work of expansion)

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