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Two compounds and with same molecular formula undergo Grignard reaction with methylmagnesium bromide to give products and . Products and show following chemical tests.
Test | C | D |
Ceric ammonium nitrate Test | Positive | Positive |
Lucas Test | Turbidity obtained after five minutes | Turbidity obtained Immediately |
Iodoform Test | Positive | Negative |
and respectively are
Solution:
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The correct answer is:

B will be ketone as it gives tertiary alcohol after reaction with grignard while A will be aldehyde which produces secondary alcohol after reaction with grignard reagent.
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