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Using the standard electrode potential, find out the pair between which redox reaction is not feasible.
$E^{\ominus}$ values $\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}=+0.77 ; \mathrm{I}_2 / \mathrm{I}^{-}=+054$
$\mathrm{Cu}^{2+} / \mathrm{Cu}=+0.34 ; \mathrm{Ag}^{+} / \mathrm{Ag}=0.80 \mathrm{~V}$
Options:
$E^{\ominus}$ values $\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}=+0.77 ; \mathrm{I}_2 / \mathrm{I}^{-}=+054$
$\mathrm{Cu}^{2+} / \mathrm{Cu}=+0.34 ; \mathrm{Ag}^{+} / \mathrm{Ag}=0.80 \mathrm{~V}$
Solution:
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Verified Answer
The correct answer is:
Ag and $\mathrm{Fe}^{3+}$
Ag and $\mathrm{Fe}^{3+}$
(a)
This reaction is feasible, since $E_{\text {cell }}^{\circ}$ is positive.
(b)
This reaction is feasible, since $E_{\text {cell }}^{\circ}$ is positive.
(c)
This reaction is feasible, since $E_{\text {cell }}^{\circ}$ is positive.
(d)
This reaction is not feasible, since $E_{\text {cell }}^{\circ}$ is negative.

This reaction is feasible, since $E_{\text {cell }}^{\circ}$ is positive.
(b)

This reaction is feasible, since $E_{\text {cell }}^{\circ}$ is positive.
(c)

This reaction is feasible, since $E_{\text {cell }}^{\circ}$ is positive.
(d)

This reaction is not feasible, since $E_{\text {cell }}^{\circ}$ is negative.
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