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Question: Answered & Verified by Expert
Vicinal and geminal dihalides can be distinguished by
ChemistryHaloalkanes and HaloarenesJEE Main
Options:
  • A KOH (aqueous).
  • B KOH (alcohol).
  • C Zn dust.
  • D None of these.
Solution:
2545 Upvotes Verified Answer
The correct answer is: KOH (aqueous).

KOH is alkaline in nature and it abstracts proton from water and attacking species OH- is formed, which works as a nucleophile.

From vicinal dihalide, it will form diols:  

CH2ClCH2ClKOHaqueousHOCH2CH2OHEthane-1, 2-diol

From gem dihalide, gem diol is formed, which converts into carbonyl compound after dehydration.

CH3CHCl2KOH aqueous gem diol H2OCH3CHOEthanal

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