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Question: Answered & Verified by Expert
What is the correct order of osmotic pressure of 0.01M aqueous solution of
(1) Al2(SO4)3
(2) K3PO4
(3) BaCl2
(4) Urea
ChemistrySolutionsNEET
Options:
  • A π4>π3>π2>π1
  • B π1>π2>π3>π4
  • C π1=π2=π3=π4
  • D π2>π4>π1>π3
Solution:
2447 Upvotes Verified Answer
The correct answer is: π1>π2>π3>π4
At same molar concentration, the osmotic pressure will depend on van't Hoff factor 'i'.
π=iCRT
i.e., more the value of 'i' more will be the value of osmotic pressure.
Thus, osmotic pressure will lie in the sequence.
π1(i=5)Al2(SO4)3>π2(i=4)K3PO4>π3(i=3)BaCl2>π4(i=1)Urea

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