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Question: Answered & Verified by Expert
What is the final chemical form of Gold (Au) when it is dissolved in aqua-regia?
Chemistryd and f Block ElementsTS EAMCETTS EAMCET 2018 (04 May Shift 2)
Options:
  • A $\mathrm{Au}$
  • B $\mathrm{AuCl}$
  • C $\mathrm{AuCl}_2$
  • D $\left[\mathrm{AuCl}_4\right]^{-}$
Solution:
1994 Upvotes Verified Answer
The correct answer is: $\left[\mathrm{AuCl}_4\right]^{-}$
When gold (Au) dissolved in aqua-regia, it forms chloroauric $\left(\mathrm{HAuCl}_4\right)$ ion. It will react very slowly with chlorin gas at room temperature to form gold chloride. We know that aqua-regia is
$$
\mathrm{Au}+\mathrm{HCl}+\mathrm{HNO}_3 \stackrel{3 \mathrm{Cl}+\mathrm{HNO}_3}{\left.\mathrm{HuCl}_4\right]^{-}}
$$

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