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Question: Answered & Verified by Expert
What product is obtained when alkyl halides react with metallic sodium in presence of dry ether?
ChemistryHaloalkanes and HaloarenesMHT CETMHT CET 2022 (08 Aug Shift 2)
Options:
  • A Alkenes with same number of carbon atoms as in alkyl halide.
  • B Alkynes with same number of carbon atoms as in alkyl halide.
  • C Alkanes with same number of carbon atoms as in alkyl halide.
  • D Alkanes with double the number of carbon atoms as in alkyl halide.
Solution:
2702 Upvotes Verified Answer
The correct answer is: Alkanes with double the number of carbon atoms as in alkyl halide.
Wurtz reaction:
This involves coupling of two identical molecules of alkyl halide upon treatment with $\mathrm{Na}$ metal in presence of dry ether to give alkanes with double the number of carbon atoms as in alkyl halide as follows:
$\mathrm{R}-\mathrm{X} \stackrel{\mathrm{Na} / \text { dry ether }}{\longrightarrow} \mathrm{R}-\mathrm{R}+\mathrm{NaX}$

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