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Question: Answered & Verified by Expert
What will be the order of reactivity of the following carbonyl compounds with Grignard's reagent?
ChemistryAldehydes and KetonesVITEEEVITEEE 2014
Options:
  • A $\quad \mathrm{I}>\mathrm{II}>\mathrm{III}>\mathrm{IV}$
  • B $\quad \mathrm{IV}>\mathrm{III}>\mathrm{II}>\mathrm{I}$
  • C $\quad \mathrm{II}>\mathrm{I}>\mathrm{IV}>\mathrm{III}$
  • D $\quad \mathrm{III}>\mathrm{II}>\mathrm{I}>\mathrm{IV}$
Solution:
2027 Upvotes Verified Answer
The correct answer is: $\quad \mathrm{I}>\mathrm{II}>\mathrm{III}>\mathrm{IV}$
As the number and the size of the alkyl groups increases, reactivity decreases. Hence, the correct order of reactivity is

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