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Question: Answered & Verified by Expert
When 20g of naphthoic acid (C 11 H 8 O 2 ) is dissolved in 50g of benzene
k f =1 .72 Kkg mol 1 , a freezing point depression of 2K is observed. The van't Hoff factor (i) is
ChemistrySolutionsNEET
Options:
  • A 0.5
  • B 1
  • C 2
  • D 3
Solution:
1602 Upvotes Verified Answer
The correct answer is: 0.5
Actual molecular weight of naphthoic acid (C 11 H 8 O 2 )=172
Molecular mass (calculated) = 1000× k f ×w W× ΔT f
= 1000 ×1.72×20 50×2 =344
van't Hoff factor (i) = actual mol.wt. calculated mol.wt. = 172 344
 =0.5

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