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Question: Answered & Verified by Expert
Which of the following spectrochemical series is TRUE?
ChemistryCoordination CompoundsJEE Main
Options:
  • A \( \mathrm{SCN}^{-} < \mathrm{NH}_{3} < \mathrm{F}^{-} < \)en \( < \mathrm{CO} \)
  • B \( \mathrm{SCN}^{-} < \mathrm{F}^{-} < \mathrm{NH}_{3} < \) en \( < \mathrm{CO} \)
  • C \( \mathrm{SCN}^{-} < \mathrm{F}^{-} < \mathrm{en} < \mathrm{NH}_{3} < \mathrm{CO} \)
  • D \( \mathrm{SCN}^{-} < \mathrm{F}^{-} < \)en \( < \mathrm{CO} < \mathrm{NH}_{3} \)
Solution:
1852 Upvotes Verified Answer
The correct answer is: \( \mathrm{SCN}^{-} < \mathrm{F}^{-} < \mathrm{NH}_{3} < \) en \( < \mathrm{CO} \)

As the electronegativity of electron donating atom increases, its electron donating tendency decreases. Hence, the correct order of spectrochemical series:

SCN-<F-<NH3<en<CO

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