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Question: Answered & Verified by Expert
Which of the following statement is correct for the reactivity in SN2 reaction?
ChemistryHaloalkanes and HaloarenesJEE Main
Options:
  • A  is more reactive than 
  • B is more reactive than
  • C  is more reactive than 
  • D  is more reactive than 
Solution:
2611 Upvotes Verified Answer
The correct answer is: is more reactive than
The electronegativity order of hybridized carbons is sp>sp2>sp3 . So in an allylic halide, such as CH2=CH-CH2-I , the alpha carbon is much more partially positive than the alpha carbon in CH3-CH2-CH2I . Therefore, the attacking nucleophile will be attracted to the alpha carbon more in the allylic halide compound than in the primary halide. Hence, allylic halides tend to follow S N 2 pathways more than primary halides.

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