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Question: Answered & Verified by Expert
Which of the given complex species is following EAN rule?
ChemistryCoordination CompoundsNEET
Options:
  • A [Ca(EDTA)]2-
  • B [Cr(en)3]3+
  • C [CoBrCl(trien)]+
  • D [Ni(dmg)2]
Solution:
2661 Upvotes Verified Answer
The correct answer is: [CoBrCl(trien)]+
EAN = Z – Oxidation number + 2× number of ligands
[Ca(EDTA)]2- 20-2+(6×2)=30
[Cr(en)3]3+ 24-3+(2×2×3)=33
[CoBrCl(trien)]+ 27-3+2+2+(4×2)=36
[Ni(dmg)2] 28-2+(4×2)=34

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