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Question: Answered & Verified by Expert
Which of these statements about [Co(CN)6]3- is true
ChemistryCoordination CompoundsNEET
Options:
  • A [Co(CN)6]3- has four unpaired electrons and will be in a low-spin configuration.
  • B [Co(CN)6]3- has four unpaired electrons and will be in a high-spin configuration.
  • C [Co(CN)6]3- has no unpaired electrons and will be in a high-spin configuration.
  • D [Co(CN)6]3- has no unpaired electrons and will be in a low-spin configuration.
Solution:
1271 Upvotes Verified Answer
The correct answer is: [Co(CN)6]3- has no unpaired electrons and will be in a low-spin configuration.
In [Co(CN)6]3- Cobalt is in + 3 oxidation state so Co+3=(Ar)3d64s04p0
As in presence of strong field ligand, pairing of electrons occurs so in this complex no unpaired electron is present and it is a low-spin complex.

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