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Why are only p-orbital electrons involved in bonding for some elements in the group 13?
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Due to the poor shielding effect of intervening d and f orbitals
Down the group, due to poor shielding effect of intervening d and f orbitals, the increased effective nuclear charge holds ns electrons tightly (responsible for inert pair effect) and thereby, restricting their participation in bonding. As a result of this, only p-orbital electron may be involved in bonding.
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