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Question: Answered & Verified by Expert

1×10-5 M AgNO3 is added to 1 L of saturated solution of AgBr. The conductivity of this solution at 298 K is _______×10-8 S m-1.

[Given : Ksp(AgBr)=4.9×10-13 at 298 K

λAg+0=6×10-3Sm2 mol-1

λBr-0=8×10-3Sm2 mol-1

λNO3-0=7×10-3Sm2 mol-1

ChemistryElectrochemistryJEE MainJEE Main 2023 (01 Feb Shift 2)
Solution:
2979 Upvotes Verified Answer
The correct answer is: 13039

The concentrations of the ions can be calculated as follows,

Ag+=10-5M

NO3-=10-5M

Br-=KspAg+=4.9×10-8M

Λm=k1000×M=Specific conductance1000×Molarity

For Ag+

6×10-3=kAg+1000×10-5

kAg+=6×10-5Sm-1

6000×10-8Sm-1

for Br-

8×10-3=kBr-1000×4.9×10-8

kBr-=39.2×10-8Sm-1

for NO3-

7×10-3=kNO3-1000×10-5

kNO3-=7×10-5Sm-1

=7000×10-8Sm-1

Conductivity of solution

(6000+7000+39.2)×10-8

13039.2×10-8 S m-1

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