$18 \mathrm{~g}$ of glucose $\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)$ dissolved in $1 \mathrm{~kg}$ of water is heated to boiling. The boiling point (in $\mathrm{K}$ ) measured at $1 \mathrm{~atm}$ pressure is closest to [Ebulioscopic constant, $K_{\mathrm{b}}$ for water is $0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$. Consider absolute zero to be $\left.-273.15^{\circ} \mathrm{C}\right]$