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Question: Answered & Verified by Expert
25 mL of 0.08 N Mohr salt solution is oxidised by 20 mL of K2Cr2O7 in acid medium. The mass of Mohr's sallt present in 500 cc is
ChemistryRedox ReactionsCOMEDKCOMEDK 2019
Options:
  • A 15.68 g
  • B 19.6 g
  • C 39.68
  • D 39.2 g
Solution:
1144 Upvotes Verified Answer
The correct answer is: 15.68 g
The reaction of Miohr's salt and K2Cr2O7 is as follow:
6Fe2++Cr2O72+14[H+]6Fe3++2Cr3++7H2O n-factor of Cr2O72 is 6 and n-factor of Fe2+ is 1 .
As n-factor for Fe is 1 so,
Molarity = Normality Concentration of Mohr's salt =0.08M
Moles in 25 mL of 0.08MMohrssalt
=0.08×251000=0.002
Moles in 500cc of Mohr's salt
=0.002×50025=0.04
Hence, mass of Mohr's salt in 500cc
=0.04×392=15.68 g

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