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Question: Answered & Verified by Expert
$A B$ is an ionic solid. The ionic radii of $A^{+}$and $B^{-}$ are respectively $r_c$ and $r_a$. Lattice energy of $A B$ is proportional to :
ChemistryThermodynamics (C)AP EAMCETAP EAMCET 2006
Options:
  • A $\frac{r_c}{r_a}$
  • B $\left(r_c+r_a\right)$
  • C $\frac{r_a}{r_c}$
  • D $\frac{1}{\left(r_c+r_a\right)}$
Solution:
1913 Upvotes Verified Answer
The correct answer is: $\frac{1}{\left(r_c+r_a\right)}$
The lattice becomes stronger (i.e., the lattice energy $U$ becomes more negative), as $r$ the inter ionic distance decreases. $U$ is proportional to $\frac{1}{r}$ or $U \propto \frac{1}{\left(r_c+r_a\right)}$

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