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A body centred cubic lattice is made up of two different types of atoms X and Y. Atom X occupies the body centre and atoms $\mathrm{Y}$ occupy the corner positions. One of the corners is left unoccupied per unit cell. The empirical formula of it is
ChemistrySolid StateTS EAMCETTS EAMCET 2023 (13 May Shift 1)
Options:
  • A $\mathrm{X}_2 \mathrm{Y}_3$
  • B $\mathrm{X}_8 \mathrm{Y}_7$
  • C $\mathrm{X}_7 \mathrm{Y}_8$
  • D $\mathrm{X}_5 \mathrm{Y}_7$
Solution:
1268 Upvotes Verified Answer
The correct answer is: $\mathrm{X}_8 \mathrm{Y}_7$
No. of X atoms per unit cell $=1 \times 8=8$

No. of $Y$ atoms per unit cell $=\left[\left(8 \times \frac{1}{8}\right) \times 8\right]-1=7$
$\Rightarrow$ Empirical formula $=\mathrm{X}_8 \mathrm{Y}_7$

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