A colorless substance ‘A’ (C 6 H 7 N) is sparingly soluble in water and gives a water soluble compound ‘B’ on treating with mineral acid. On reacting with CHCl 3 and alcoholic potash ‘A’ produces an obnoxious smell due to the formation of compound ‘C’. Reaction of ‘A’ with benzenesulfonyl chloride gives compound ‘D’ which is soluble in alkali. With NaNO 2 and HCl, ‘A’ forms compound ‘E’ which reacts with phenol in alkaline medium to give an orange dye ‘F’. Identify compounds ‘A’ to ‘C’.

Question

A colorless substance ‘A’ (C 6 H 7 N) is sparingly soluble in water and gives a water soluble compound ‘B’ on treating with mineral acid. On reacting with CHCl 3 and alcoholic potash ‘A’ produces an obnoxious smell due to the formation of compound ‘C’. Reaction of ‘A’ with benzenesulfonyl chloride gives compound ‘D’ which is soluble in alkali. With NaNO 2 and HCl, ‘A’ forms compound ‘E’ which reacts with phenol in alkaline medium to give an orange dye ‘F’. Identify compounds ‘A’ to ‘C’., A = Phenol, B = Anilium chloride , C = Benzene isonitrile, A = Aniline, B = Anilium chloride , C = Benzene, A = Aniline, B = Benzene , C = Benzene isonitrile, A = Aniline, B = Anilium chloride , C = Benzene isonitrile

MARKS App · Accepted Answer

Correct Option is : (D) A = Aniline, B = Anilium chloride , C = Benzene isonitrile

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