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Question: Answered & Verified by Expert
$A$ forms $h c p$ lattice and $B$ are occupying $1 / 3^{\text {rd }}$ of tetrahedral voids, then the formula of compound is
ChemistrySolid StateAIIMSAIIMS 2014
Options:
  • A $A B$
  • B $A_3 B_2$
  • C $A_2 B_3$
  • D $A B_4$
Solution:
2954 Upvotes Verified Answer
The correct answer is: $A_3 B_2$
Let no. of atoms of $A$ used in close packing$=n$
Number of tetrahedral voids $=2 n$
Number of atoms of $B=\frac{1}{3} \times 2 n=\frac{2}{3} n$
$A: B=n: \frac{2}{3} n=3: 2$
Formula of the compound $=A_3 B_2$

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