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Question: Answered & Verified by Expert

A gaseous hydrocarbon on combustion gives 0.72 g of water and 3.08 g CO2. What is the empirical formula of the hydrocarbon?

ChemistrySome Basic Concepts of ChemistryJEE MainJEE Main 2013 (07 Apr)
Options:
  • A C6H5
  • B C7H8
  • C C2H4
  • D C3H4
Solution:
2208 Upvotes Verified Answer
The correct answer is: C7H8

C x H y + x + y 4 O 2 xC O 2 + y 2 H 2 O

Moles of CO2 = 3 . 0 8 4 4 = 0 . 0 7  moles = x

Moles of H2O = 0 . 7 2 1 8 = 0 . 0 4  moles = y 2

x = 0.07 g atoms of carbon

y = 0.08 g atoms of hydrogen

   x       :        y0.07        0.08   7              8

Empirical formula becomes C7H8.

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