Miscible mixture of ${\text{C}}_{\text{6}}{\text{H}}_{\text{6}}\text{+}{\text{CHCl}}_{\text{3}}$ can be separated by distillation method due to the significant difference in their boiling points. Boiling point of Benzene is $\text{80}{\text{.1}}^{\text{o}}\text{C}$ while that of chloroform is $\text{61}{\text{.2}}^{\text{o}}\text{C}$.