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Question: Answered & Verified by Expert
A red solid is insoluble in water. However, it becomes soluble if some KI is added to water. Heating the red solid in a test tube results in liberation of some violet coloured fumes and droplets of a metal appear on the cooler parts of the test tube. The red solid is
ChemistryPractical ChemistryJEE Main
Options:
  • A HgI2
  • B HgO
  • C Pb3O4
  • D NH42Cr2O7
Solution:
2225 Upvotes Verified Answer
The correct answer is: HgI2
HgI2 is orange-red in appearance and hardly soluble in water. It dissolves in excess of I- giving complexes HgI3- and HgI42- . Violet fumes are liberated due to the release of Iodine gas upon heating.

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