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Question: Answered & Verified by Expert
Acetic acid ( CH3COOH ) is partially dimerised to CH3COOH2 in the vapour phase. At a total pressure of 0.200atm , acetic acid is 92.0% dimerized at 298K . The value of equilibrium constant of dimerization under these conditions is
ChemistryChemical EquilibriumJEE Main
Options:
  • A 57.5 atm 1
  • B 9.7 atm 1
  • C 97 atm 1
  • D 194 atm 1
Solution:
2842 Upvotes Verified Answer
The correct answer is: 194 atm 1

According to question; 0.46a+0.08a=0.2
a= 0.2 0.54
K P = 0.46× 0.2 0.54 0.08× 0.2 0.54 2
=194 atm 1

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