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Question: Answered & Verified by Expert
$\mathrm{Al}$ (at. wt 27 ) crystallizes in the cubic system with a cell edge of $4.05 Ã…$. Its density is $2.7 \mathrm{~g}$ per $\mathrm{cm}^{3}$. Determine the unit cell type calculate the radius of the $\mathrm{Al}$ atom
ChemistrySolid StateBITSATBITSAT 2016
Options:
  • A $\mathrm{fcc}, 2.432 Ã$
  • B bcc, $2.432 Ã$
  • C bcc, $1.432 Ã$
  • D $\mathrm{fcc}, 1.432 Ã$
Solution:
1774 Upvotes Verified Answer
The correct answer is: $\mathrm{fcc}, 1.432 Ã$
$\rho=\frac{Z \times M}{N_{0} \times a^{3}}$,

$$

2.7=\frac{Z \times 27}{6.02 \times 10^{23} \times(4.05)^{3} \times 10^{-24}}

$$

$\therefore Z=4$

Hence it is face centred cubic unit lattice.

Again $4 r=a \sqrt{2}=5.727 Ã…$

$\therefore \mathrm{r}=1.432 Ã…$

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