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Amongst LiCl, RbCl, BeCl2 and MgCl2 the compounds with the greatest and the least ionic character, respectively are :
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RbCl and BeCl2
(i) % Ionic character = 16(XA – XB) + 3.5 (XA – XB)2
, ,
For and the electronegativity difference is highest so having more ionic character. For , electronegativity difference is the lowest so having less ionic character
Covalent character in compound depends upon the charge and size of ions. As charge in cation increases, covalent character increases and as size of cation increases covalent character decreases. Charge factor dominate over size factor. Since has higher charge and smallest size therefore, has maximum covalent character and least ionic character
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