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Question: Answered & Verified by Expert
Aqueous solution of orthoboric acid can be titrated against sodium hydroxide using phenolphthalein indicator only in presence of:
ChemistryRedox ReactionsJEE Main
Options:
  • A trans-glycerol
  • B catechol
  • C cis-glycerol
  • D both B and C
Solution:
2017 Upvotes Verified Answer
The correct answer is: both B and C
It forms a stable cyclic complex with polyhydroxy compounds like cis-glycerol, catechol, etc. This helps in the release of H+as H3O+ therefore, boric acid acts as a strong acid and hence can be titrated with sodium hydroxide using phenolphthalein.

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