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Question: Answered & Verified by Expert
Assertion : Greater the value of van der Waals' constant ' $a$ ' greater is the liquefaction of gas. Reason : ' $a$ ' indirectly measures the magnitude of attractive forces between the molecules.
ChemistryStates of MatterAIIMSAIIMS 2018 (26 May)
Options:
  • A If both assertion and reason are true and reason is the correct explanation of assertion.
  • B If both assertion and reason are true but reason is not the correct explanation of assertion.
  • C If assertion is true but reason is false.
  • D If both assertion and reason are false.
Solution:
2575 Upvotes Verified Answer
The correct answer is: If both assertion and reason are true and reason is the correct explanation of assertion.
Considering the attractive force pressure, the ideal gas equation $(P V=n R T)$ is corrected by introducing a factor of $\frac{a n^2}{V^2}$ where $a$ is van der Waals constant.

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