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Question: Answered & Verified by Expert
Assertion : $\mathrm{H}_3 \mathrm{PO}_2$ has strong reducing property but $\mathrm{H}_3 \mathrm{PO}_4$ does not.Reason : $\mathrm{P}-\mathrm{OH}$ bond present in $\mathrm{H}_3 \mathrm{PO}_4$.
Chemistryp Block Elements (Group 15, 16, 17 & 18)AIIMSAIIMS 2012
Options:
  • A If both assertion and reason are true and reason is the correct explanation of assertion
  • B If both assertion and reason are true but reason is not the correct explanation of assertion
  • C If assertion is true but reason is false
  • D If both assertion and reason are false.
Solution:
2556 Upvotes Verified Answer
The correct answer is: If both assertion and reason are true but reason is not the correct explanation of assertion



Oxoacids of phosphorus which contain $\mathrm{P}-\mathrm{H}$ bond act as reducing agents and reduce metal salts to free metals. Thus, $\mathrm{H}_3 \mathrm{PO}_2$ act as reducing agent while $\mathrm{H}_3 \mathrm{PO}_4$ does not.

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