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Question: Answered & Verified by Expert
Boiling point of a 2% aqueous solution of a nonvolatile solute A is equal to the boiling point of 8% aqueous solution of a non-volatile solute B. The relation between molecular weights of A and B is.
ChemistrySolutionsJEE MainJEE Main 2022 (27 Jul Shift 1)
Options:
  • A MA=4MB
  • B MB=4MA
  • C MA=8MB
  • D MB=8MA
Solution:
2483 Upvotes Verified Answer
The correct answer is: MB=4MA

For A : 100gm solution 2gm solute A Molality =2/MA0.098

For B : 100gm solution 8gm solute B Molality =8/MB0.092

 ΔTBA=ΔTBB

Molality of A= Molality of B

20.098MA=80.092MB

298×928=MAMB

14.261=MAMB

 MB=4.261×MA

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