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Question: Answered & Verified by Expert
Calculate osmotic pressure of $0.2 \mathrm{M}$ aqueous $\mathrm{KCl}$ solution at $0^{\circ} \mathrm{C}$ if van't Hoff factor for $\mathrm{KCl}$ is $1.83 .\left[\mathrm{R}=0.082 \mathrm{dm}^3\right.$ atm mol$\left.{ }^{-1} \mathrm{~K}^{-1}\right]$
ChemistrySolutionsMHT CETMHT CET 2023 (11 May Shift 2)
Options:
  • A $8.2 \mathrm{~atm}$
  • B $9.4 \mathrm{~atm}$
  • C $10.6 \mathrm{~atm}$
  • D $6.5 \mathrm{~atm}$
Solution:
1045 Upvotes Verified Answer
The correct answer is: $8.2 \mathrm{~atm}$
$\begin{aligned} \pi & =\mathrm{iMRT} \\ & =1.83 \times 0.2 \times 0.082 \times 273 \\ & =8.2 \mathrm{~atm}\end{aligned}$

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