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Question: Answered & Verified by Expert
If $38 \cdot 55 \mathrm{~kJ}$ of heat is absorbed when $6 \cdot 0 \mathrm{~g}$ of $\mathrm{O}_{2}$ react with CIF according to reaction $2 \mathrm{CIF}_{(\mathrm{g})}+\mathrm{O}_{2(\mathrm{~g})} \longrightarrow \mathrm{Cl}_{2} \mathrm{O}_{(\mathrm{g})}+0 \mathrm{~F}_{2}(\mathrm{~g})$
What is the standard enthalpy of reaction?
ChemistryThermodynamics (C)MHT CETMHT CET 2020 (16 Oct Shift 1)
Options:
  • A $72.28 \mathrm{~K}$
  • B $205.6 \mathrm{k} \mathrm{J}$
  • C $102.8 \mathrm{k}]$
  • D $49.80 \mathrm{k}]$
Solution:
2287 Upvotes Verified Answer
The correct answer is: $205.6 \mathrm{k} \mathrm{J}$
(A)
$\begin{array}{l}
2 \mathrm{ClF}_{(\mathrm{g})}+\mathrm{O}_{2(\mathrm{~g})} \longrightarrow \mathrm{Cl}_{2} \mathrm{O}_{(\mathrm{g})}+\mathrm{OF}_{2(\mathrm{~g})} \\
\text { For } 6.0 \mathrm{~g} \text { of } \mathrm{O}_{2} \Rightarrow \Delta \mathrm{H}=+38.55 \mathrm{~kJ} \\
\therefore \text { For } 32.0 \mathrm{~g} \text { of } \mathrm{O}_{2} \Rightarrow \Delta \mathrm{H}^{0}=\frac{38.55 \times 32}{6}=205.6 \mathrm{~kJ}
\end{array}$

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