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Question: Answered & Verified by Expert
If a centimolal aqueous solution of $\mathrm{K}_{3}\left[\mathrm{~F}_{\mathrm{e}}(\mathrm{CN})_{6}\right]$ has degree of dissociation $0 \cdot 78$, what is the value of vant Hoff factor?
ChemistrySolutionsMHT CETMHT CET 2020 (16 Oct Shift 1)
Options:
  • A 3.34
  • B 1.2
  • C 2.5
  • D 4.0
Solution:
2917 Upvotes Verified Answer
The correct answer is: 3.34
(A)
$\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right] \longrightarrow 3 \mathrm{~K}^{+}+\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{-}$
$\therefore \mathrm{n}=4$
van't Hoff factor (i) $=1+\alpha(n-1)=1+0.78(4-1)=3.34$

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