Let, the cone is obtained by rotating about $BC$

From the diagram, the radius of the cone is $AB$ and the height is $BC$
The volume generated, $V=\frac{1}{3}\pi r^{2}h=\frac{1}{3}\pi \left(4-x^2\right)\left(x\right)$
For maximum volume, $\frac{dV}{dx}=0$
$\Rightarrow 4-3x^2=0\Rightarrow x=\frac{2}{\sqrt{3}}$

 $\therefore V_{\mathrm{m}\mathrm{a}\mathrm{x}}=\frac{\pi }{3}\left(4-\frac{4}{3}\right)\frac{2}{\sqrt{3}}=\frac{16\pi }{9\sqrt{3}}$
Also, $\frac{d^{2}V}{d{x}^2}<0$

Hence, $x\left(4-x^2\right)=\frac{2}{\sqrt{3}}\left(4-\frac{4}{3}\right)=\frac{16}{3\sqrt{3}}$