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Question: Answered & Verified by Expert
In chromite ore, the oxidation number of iron, and chromium are respectively
ChemistryGeneral Principles and Processes of Isolation of MetalsKCETKCET 2010
Options:
  • A $+3,+2$
  • B $+3,+6$
  • C $+2,+6$
  • D $+2,+3$
Solution:
2703 Upvotes Verified Answer
The correct answer is: $+2,+3$
Chromite or chrome iron ore is $\mathrm{FeCr}_{2} \mathrm{O}_{4}$. Its actual composition is $\mathrm{FeO} \cdot \mathrm{Cr}_{2} \mathrm{O}_{3}$.
In $\mathrm{FeO}$, oxidation state of $\mathrm{Fe}$ is calculated as
$$
\begin{aligned}
\mathrm{x}+(-2) &=0 \\
\mathrm{x} &=+2
\end{aligned}
$$
Similarly, in $\mathrm{Cr}_{2} \mathrm{O}_{3}$, the oxidation state of $\mathrm{Cr}$ is calculated as
$$
\begin{aligned}
2 \times x+(-2) \times 3 &=0 \\
2 x &=+6 \\
x &=+3
\end{aligned}
$$

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