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Question: Answered & Verified by Expert
In Hall-Heroult process, the following is used for reducing Al2O3 :-
ChemistryGeneral Principles and Processes of Isolation of MetalsJEE MainJEE Main 2023 (08 Apr Shift 2)
Options:
  • A Magnesium
  • B Na3AlF6
  • C Graphite
  • D CaF2
Solution:
2251 Upvotes Verified Answer
The correct answer is: Graphite

The process of extracting Al metal by electrolysis of a mixture of purified Al2O3 and Na3AlF6 is known as Hall and Heroult process.
Graphite is used as anode which is useful in the reduction of alumina oxide to the Al metal. The graphite electrode reacts with the oxygen released at cathode to form carbon dioxide and carbon monoxide.
Therefore, the role of graphite as an anode in the extraction of Al is to check the formation of oxygen. In other words, we can say its role is to prevent the oxidation of Al back to Al2O3 by oxygen.

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