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Question: Answered & Verified by Expert
In reaction $\mathrm{A}+2 \mathrm{~B} \rightleftharpoons 2 \mathrm{C}+\mathrm{D}$, initial concentration of $\mathrm{B}$ was $1.5$ times of $\mathrm{[A]}$, but at equilibrium the concentrations of $\mathrm{A}$ and $\mathrm{B}$ became equal. The equilibrium constant for the reaction is :
ChemistryChemical EquilibriumJEE MainJEE Main 2013 (09 Apr Online)
Options:
  • A
    $8$
  • B
    $4$
  • C
    $12$
  • D
    $6$
Solution:
1651 Upvotes Verified Answer
The correct answer is:
$4$


Hence $\mathrm{K}_{\mathrm{C}}=\frac{(2 x)^2 \times x}{(a-x)(1.5 a-2 x)^2}$
Given, at equilibrium
$\begin{array}{ll}\therefore & (a-x)=(1.5 a-2 x) \\ \therefore & a=2 x\end{array}$
On solving $K_C=4$

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